Yes, this works in the same way as with a mobile phone. But check whether your PC already has a Bluetooth module built in. Today, most of those that also have a built-in WLAN adapter already have this integrated.
You can connect the headphones via "Settings -> Devices -> Bluetooth".
A small tip: if you don't have a BT in your PC yet, I recommend connecting the adapter to a front USB or monitor (if it has USB), as the metal housing usually dampens the radio signals very strongly, which can lead to dropouts.