Can the Western Digital hard disks of a previously used Synology DS212j network storage be inserted into the Synology DS223j empty enclosure in a functioning manner, i.e. are they compatible in that they are recognised and the network storage can still be booted up and used as usual?

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Answer

I ask you to check if the exact model of the hard drive can be found on the compatibility list: 
https://www.synology.com/de-de/compatibility?search_by=products&model=DS223j&category=hdds_no_ssd_trim&display_brand=other

If it is there, it is compatible.

Your data. Your choice.

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Question about Synology DS223j

Can the Western Digital hard disks of a previously used Synology DS212j network storage be inserted into the Synology DS223j empty enclosure in a functioning manner, i.e. are they compatible in that they are recognised and the network storage can still be booted up and used as usual?